SYSTEMS OF REFRIGERATION BY ABSORPTION - METROGAS

THE COMPANY

On 29 December 1992, MetroGas took over gas distribution for 35 years—renewable for another 10 years—within an area of 2,150 square kilometers, including the capital city of Buenos Aires and the nine districts comprising the southern part of Greater Buenos Aires. This area has a population of seven million, which represents 21% of Argentina's total population.

MetroGas serves approximately 1,850,000 customers, with an average annual demand of 6,000 million cubic meters, representing 25% of Argentina's total consumption. The company’s network of low-and high-pressure pipelines is 13,000 kilometers long and has more than 900,000 utility service lines.

THE PROJECT

Abiding by the principles of ecoefficiency, which produce financial benefits and link businesses together in their work for environmental preservation, MetroGas has promoted the use of natural gas as an energy source for air conditioning in buildings.

As a part of this effort, the company decided to install a 240-ton-capacity refrigeration system at its central headquarters. MetroGas studied the options available on the market and chose absorption air conditioning, which uses lithium bromide (LiBr) as an absorbent, with water as a refigerant. This technology decreases environmental impact by complying with the guidelines for reducing the use of refrigerant gases, which contribute to the greenhouse effect.

THE COOLING PROCESS

The Traditional Process

In the traditional cooling process, a liquid circulates through a coil to absorb the heat that is present. If the liquid is within a vacuum packed system, its temperature drops due to the fact that the liquid gives up its energy content, thereby lowering the temperature of the medium. This process involves the input of a certain amount of heat, which is consumed as the liquid turns into vapor at a constant temperature and pressure. When the pressure drops, evaporation temperature decreases approximately 4°C at a pressure of 0.01 atm.

The process during which a liquid expands and becomes vapor can occur in several different ways. The most common involves the compression of refrigerant compounds, which may be halogenated hydrocarbons commonly known as Freons, at more than ten times atmospheric pressure. When this occurs, the refrigerant heats up and produces vapor, which then becomes liquid because the ambient temperature cools it, thus eliminating the heat caused by the compression effort from the medium. The liquid refrigerant expands within a closed system, which is in contact with the space to be cooled, and begins the refrigeration cycle again.

The Ecoefficient Process

In the case of absorption with LiBr, water is the substance that is compressed and expanded. At ambient temperature, the concentrated LiBr solution requires water to remain stable, and it absorbs the vapor as though it were the compressor in the traditional process. The following illustration shows the absorption stage of the process:

The concentrated 65% LiBr solution is mixed with water vapor and becomes diluted to 60%. This dilution-absorption action causes a vacuum in the vapor area and an increase in the volume of liquid. The diluted solution is sent via pump to a generator, where it is heated to concentrate the LiBr salt and begin the process again. The energy required for the concentration of salt and evaporation of water is equivalent to the energy used to compress refrigerant vapor in the traditional system.

To reach its liquid state again, the water vapor must lose part of its non-useable energy. This reaction occurs in a condenser, through which water is circulated at 29.5°C in order to regenerate the evaporation cycle. In this cycle, water is evaporated by the vacuum effect generated by the absorber. Air cooled to 15°C is extracted from a water loop at a temperature of 7°C to service the building that is being air conditioned.

ECOEFFICIENT STRATEGY

When air conditioning its headquarters, MetroGas ruled out the use of refrigerants that damage the ozone layer and contribute to global warming. The company adopted the LiBr absorption technology, due to the fact that it works with natural refrigerants such as water and a salt (LiBr), which, when vacuum-packed within the equipment, do not present any hazards to the environment.

If MetroGas had installed a traditional air conditioning system, the company would have had to use approximately 240 kilograms of environmentally unfriendly refrigerants, such as chlorinated and/or fluoridated (halogenated) products. They also would have run the risk of refrigerant leakage through seals and/or total leakage, if part of the system were damaged or if the equipment were taken out of service.

RESULTS

As can be seen in the following comparative table for both processes, for the same number of hours per year of cooling equipment use at full load, the alternative of a LiBr absorption air conditioning system provides an operating savings of approximately U.S.$14,700. Although the cost of these absorption systems is higher than for compression systems with the same capacity, this difference is offset within a short time, due to lower operating and maintenance costs.

Comparison of Cooling Processes

Variable

Traditional Process

LiBr Absorption Process

Electric Power (kW)

                224

      45

Hours of Operation (h/year)

            1,000

                      1,000

Electric Power Consumption (kWh/year)

        224,000

                    45,000

Natural Gas Consumption (nm3/year)

   0

                    76,800

Cost of Electric Power (U.S.$/year)

          30,400

                      6,100

Cost of Natural Gas (U.S.$/year)

  0

   9,600

Total Cost  (U.S.$/year)

          30,400

                     15,700

Operating Savings (U.S.$/year)

-

                     14,700

For an air conditioning system providing 240 tons of refrigeration, traditional equipment uses approximately 224 kW of power, whereas absorption units use 45 kW. As a result, not only are electrical system requirements minimized, but so are the hazards involved in handling high current loads, the heat losses due to the Joule effect, and the reactive power that must be compensated for. Absorption equipment requires less power from an alternative source in order to operate without a utility network.

The lower energy use shown by absorption equipment can also be observed in the comparative table. Its performance coefficient (PC), which relates energy consumed to energy actually taken advantage of, is close to 1. On the other hand, compression equipment units driven by electricity and using halogenated refrigerants have a PC of around 4.5. It must be realized that in a traditional air conditioning system, 75% of fuel energy is wasted when it is transformed into electricity, whereas in the absorption system, only 10% of the energy from the natural gas being used is wasted.

BENEFITS OF THE PROJECT

Following are some of the project’s benefits:

  • Use of refrigerants unfriendly to the environment is avoided.
  • LiBr can be marketed after it has been in the process, because it is an easily recovered stable salt with good resale value.
  • Savings are achieved on a long-term basis, according to cost recovery time, due to the fact that the absorption method is cheaper than the traditional method.
  • Lower operating costs are assured.
  • Dependence on the absorption units of electric power networks is circumvented, given their low power consumption.
  • Proper system functioning is assured during the summer, because this equipment compensates for energy demand by using it when the maximum flow of gas is available.
  • Increased durability and less maintenance are assured with this equipment because of its proper design.
  • Noise is eliminated, and therefore even more money is saved because sound insulation is unnecessary.
  • Complete, optimum use is made of this equipment because it serves both heating and cooling  purposes.
CONCLUSIONS

The absorption system has been in use for more than forty years in Argentina. From the experience that has been gained, it has been shown that the useful life of equipment of this kind is longer, which more than compensates for whatever cost difference there may be when compared to that of traditional air conditioning equipment. When its lower energy requirements and the proven advantages of greater friendliness to the environment are added to the abovementioned factors, it can be predicted that systems of this kind will eventually replace others currently in use.

CONTACT

Fernando Iuliano
MetroGas
Magallanes 1491, PB
1267 Buenos Aires, Argentina
Tel. (54-11) 4309 1685
Fax (54-11) 4309 1680